甲基丙烯酸甲酯论文：活性炭吸附消除PMMA裂解工艺废气的研究.docVIP

甲基丙烯酸甲酯论文：活性炭吸附消除PMMA裂解工艺废气的研究 【中文摘要】本文从解决浙江某镇废旧有机玻璃回收再生行业的含挥发性有机化合物废气排放问题出发，选择活性炭吸附消除技术进行研究，通过研究选择了一种颗粒活性炭作为吸附剂，并确定了最佳的吸附工艺操作条件。在此基础上，对活性炭吸附过程中挥发性酯类竞争吸附现象进行了初步的研究和探讨。首先，论文通过筛选确定颗粒活性炭为吸附剂，并系统地考察了进气浓度、质量空速、床层温度以及相对湿度的变化对其吸附纯组分甲基丙烯酸甲酯性能的影响，同时对活性炭重复再生性能进行考察。结果表明，活性炭对甲基丙烯酸甲酯吸附性能较好，干气条件下，进气浓度为1000mg/m~3时，活性炭饱和吸附量为0.234g/g，进气浓度小于1000mg/m~3时，吸附量下降明显；湿度对活性炭吸附能力有一定影响，相对湿度为50%时，活性炭对甲基丙烯酸甲酯吸附量保持在80%以上，增加进气浓度有利于活性炭吸附湿气中的甲基丙烯酸甲酯。由于活性炭吸附甲基丙烯酸甲酯为放热过程，0℃时吸附效果较好，升高温度不利于吸附过程的进行。根据实验确定，该活性炭的最佳工艺操作条件为：进气浓度1000mg/m~3、空速30000mL/(h2g)、作业温度为30℃。经多次重复再生考察，活性炭吸附效果未见明显下降，表明其再生性能良好。接下来,本文对甲基丙烯酸甲酯、乙酸乙酯、甲酸甲酯、丙烯酸甲酯在活性炭及改性活性炭上的竞争吸附行为进行了考察。结果显示,活性炭上选择性吸附规律与有机物熔沸点和极性以及活性炭表面基团相关。有机物熔点越低、沸点越高,非极性趋势越强,越容易在竞争吸附中被活性炭吸附。上述有机物吸附能力强弱依次为:甲基丙烯酸甲酯丙烯酸甲酯乙酸乙酯甲酸甲酯。改性处理后的活性炭表面官能团发生变化,酸改性处理后活性炭表面碱性基团减少,可提高活性炭对酯类化合物竞争吸附中强吸附质的选择性,碱改性处理后结果与酸改性处理相反。根据上述情况,设计多段吸附工艺,为处理实际工艺废气提供帮助。 【英文摘要】The research focused on the selection of a sorbent which could beadsorption functions for VOCs waste gas treatment and provided the besttechnical conditions issues from plexiglass recycling regenerationindustry in Zhejiang Province. Based on the experiment data, the rule ofcompetition adsorption phenomenon for the active carbon treatmentprocess would be future dicussed in the paper.Firstly, the research chose active carbon as the sorbent for adsoptionand systematically analyzed the inlet gas flow component methylmethacrylate in the aspects of concentration, bed temperature level, thegas space velocity and the relative humidity to influence of adsorptionconditions by active carbon. And the active carbon redundantreproductive properties are inspected as well. The results show activecarbon has a better performance in methyl methacrylate. Under thecondition of dry gas flow, it adsorbed 0.234g/g on condition that theconcentration was 1000mg/m3. However, adsorptive capacity declinedobviously when the concentration was less than 1000mg/m3. Morever, the humidity influenced on adsorptive capacity of active carbon as well. When the relative humidity