纳米pdπfe双金属对242二氯酚的脱氯机理及动力学-环境科学学报.pdfVIP

第 24 卷第 4 期 环 　境 　科 　学 　学 　报 Vol . 24 ,No . 4 2004 年 7 月 ACTA SCIENTIAE CIRCUMSTANTIAE July ,2004 ( ) 文章编号 2004 　　　中图分类号 :X13 　　　文献标识码 :A 纳米 PdFe 双金属对 2 ,4二氯酚的脱氯机理及 动力学 ( ) 徐新华 　金 　剑 　卫建军 　汪大　　 浙江大学环境工程系 , 杭州 　310027 ( ) 摘要 :采用纳米 PdFe 双金属对 2 ,4二氯酚 2 ,4DCP 进行了催化还原脱氯处理. 结果表明,纳米 PdFe 双金属具有较高的比表 面积和反应活性 ,对 2 ,4DCP 具有较好的脱氯效率. 当纳米 PdFe 用量在 6g ·L - 1 时 ,2 ,4DCP 脱氯率达到 90 %以上 ;脱氯效率与 p H 值、温度、钯化率、PdFe 投加量等因素有关. 2 ,4DCP 在脱氯过程中先生成邻氯酚和对氯酚 ,而后继续脱氯生成苯酚 ,或由 2 ,4DCP 直接降解成苯酚. 2 ,4DCP 降解符合拟一级反应动力学.2 ,4DCP 催化还原脱氯反应的活化能为 1397 kJ ·mol - 1 . 关键词 :纳米 PdFe 双金属 ; 2 ,4二氯酚 ;脱氯 ;机理 ;动力学 Dechlorination mechanism and kinetic of 2 ,4DCP by nanoscale PdFe system ( XU Xinhua , J IN Jian , WEI Jianj un , WANG Dahui 　 Department of Environmental Engineering , Zhejiang University , Hangzhou 　310027) Abstract :Nanoscale PdFe bimetallic catalysts were synthesized via chemical deposition and used to decompose 2 ,4DCP. Nanoscale particles were characterized by high surface area to volume ratios and high reactivity. Batch experiments demonstrated that the nanoscale PdFe particles could effectively dechlorinate 2 ,4DCP at relatively low metal to solution ratio (6g ·L - 1 ) , Dechlorination efficiency reached 90 % at Pd weight ratio (Pd to Fe) 0 . 11 %. Dechlorination was affected by reaction temperature , p H , Pd ratio and the addition of nanoscale PdFe . 2CP and 4CP represent stable partially dechlorination intermediates , and then phenol . Some 2 ,4DCP was dechlorinated to phenol ind