热处理对PMMAPCM纳米胶囊相变特性的影响及机理.PDF

80 材料导报B:研究篇 2011 年3 月( 下) 第25 卷第3 期 PMMA@ PCM * 1,2 1 1 3 吴晓琳 , 孙 蓉 , 朱朋莉 , 杜如虚 ( 1 , 518055;2 , 100049; 3 , 999077) 采用界面聚合法制备了以石蜡为芯材聚甲基丙烯 甲酯为壳层的纳米胶囊相变材料胶囊的直径为 100~ 400nm, 相变焓可达29J/ g, 封装比率约为35% 采用差示热扫描量热仪( DSC) 对PMMA@ PCM 经40 60 及100 热处理后相变特性的变化进行了探讨结果显示, 随着热处理时间的延长, 相变温度均有所升高凝固温度 的升高是由于胶囊表面形成了一定量的相变晶种,而熔化温度的升高则是由于纳米胶囊体积的增加而引起的热传导 率降低这 一研究结果将有助于分析纳米胶囊相变过程的微结构变化理论 : T 522. 1 :A The Effect of Heat Treatment on the Phase Transition Characteristics of PMMA@PCM Nanocapsules and the Mechanism 1,2 1 1 3 W Xiaolin , S N Rong , ZH Pengli , D Ruxu ( 1 Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055; 2 Graduate niversity of Chinese Academy of Sciences, Beijing 100049; 3 T he Chinese niversity of Hong Kong,Hongkong 999077) Abstract T he interfacial polymerization method was used to prepare nanocapsules with paraffin as the core and PMMA as the shell. The particle size of capsules was 100~ 400nm with the latent heat of ~ 29J/g and the encap sulation ratio of ~ 35%. Differential scanning calorimeter(DSC) was used to study the effect of heat treatment situa tion, such as at 40 , 60 and 100 , on the phase transition characteristics of PMMA@ PCM. The analysis show s that with the heat treating time increasing, the phase change temperatures all increase. T he increase of freezing tem perature should be the aggregation of crystal seed in the surface of the capsules. The improving of melting temperature should be the increasing of capsule volume, which will decrease the pyroconductivity of capsules. T hese analysis re sults are helpful for the study of microstructure