塑料管材输配水过程中有机物释放规律研究.pdfVIP

中国环境科学 2014,34(6) ：1478~1484 China Environmental Science 塑料管材输配水过程中有机物释放规律研究 * 张 玲,刘书明 ,胡洪营 (清华大学环境学院,北京 100084) 摘要：研究了目前给水管网中常用的 3 种塑料管材,未增塑聚氯乙烯(uPVC),聚乙烯(PE)和无规共聚聚丙烯(PPR)管在输配水过程中有机物 的释放规律.通过静态管段实验模拟给水管网中不同输配水状态,选取总有机碳(TOC)为综合评价指标,考察了不同塑料管材中有机物随时 间的迁移释放特性,并分析了管材有机物释放对管网水中余氯消耗的影响.随着管材输配水次数的增加,uPVC 管释放至水中的 TOC 浓度和 TOC 释放速率分别在 0.03mg/L 和 0.04µg/(d·cm2) 以下,而 PE 管和 PPR 管在输配水过程中 TOC 的释放浓度和释放速率在初期最大[PE: 2 2 2 0.19mg/L,0.25µg/(d·cm );PPR:0.07mg/L,0.09µg/(d·cm )],且后期递减并趋于平稳[PE:0.03~0.08mg/L,0.05~0.10µg/(d·cm );PPR:0.01~0.03mg/L, 0.01~0.04µg/(d·cm2)].随着水力停留时间的增加,不同管材释放的有机物浓度持续升高.不同管材有机物的释放能力排序为:PEPPRuPVC. 各管材的有机物释放特性直接影响管网水的余氯消耗特性,且管材的有机物释放量越多,管网水的余氯消耗越快.PE 管的使用易引起水体 有机污染问题.本研究明确了 3 种常用塑料管材的有机物释放规律,将进一步为与塑料管材安全性能评价相关的国家标准的修订提供理论 依据. 关键词：塑料管材；释放；总有机碳；余氯消耗；饮用水 中图分类号：X832 文献标识码：A 文章编号：1000-6923(2014)06-1478-07 * Research of organic compounds migration from polymeric pipes. ZHANG Ling, LIU Shu-ming , HU Hong-ying (School of Environment, Tsinghua University, Beijing 100084, China). China Environmental Science, 2014,34(6)：1478~1484 Abstract ：Polymeric pipes, such as unplasticized polyvinyl chloride pipe (uPVC), polypropylene random pipe (PPR) and polyethylene pipe (PE) are increasingly used for drinking water distribution networks. This work was designed to determine the TOC migration characteristics of three types of polymer pipes (uPVC, PE and PPR) into drinking water and investigate the influence of TOC migration on the chlorine decay in water. Migration tests were carried out under stagnant conditions with different migration times to simulate drinki