土壤中五氯酚的快速测定.pdfVIP

2008 4 V o l. 27, N o. 2 A pr il 2008 ROCK AND M IN ERA L ANALY SIS 117 ~ 119 : 0254 - 5357 2008) 02- 0 117 - 0 3 土壤中五氯酚的快速测定 * 肖宇芳, 刘广民 , 董永亮, 尹莉莉 , 150001) : 针对五氯酚 PCP )污染土壤, 根据 N aOH 与五氯酚反应生成五氯酚钠的原理, 不易溶 于水的PCP 与碱液反应生成易溶于水的盐类, 从而达到从土壤中提取五氯酚的目的用紫外分光 光度法定量测定五氯酚含量,确定出最佳提取与分析条件结果表明, PCP - N a合适的紫外吸收波 长为 319 nm; 在 300 r/m in振荡时, 最佳提取条件为提取液 pH 12. 5土液比为 1 8 g /mL)提取 时间为20 m in在此条件下, 加标回收率为 91. 2% ~ 116. 7% , 最低检测限为 2 g /mL方法快速 简便, 适合于农田土壤中五氯酚的现场检测 : 五氯酚; 紫外分光光度法; 土壤; 快速测定 : O625. 31; O657. 32 : A Rapid Determ ination of Pentachlorophenol in Soil Samples * X IA O Yuf ang, LI U Guang m in , DON G Yong liang, YIN L ili ( Depa rtm ent o f Env ironm enta l Eng inee ring, Co llege o f M ate ria l S c ience and Chem ica l Eng ineering, Harb in Eng inee ring Un ive rs ity, Harb in 150001, Ch ina) Abstract: Based on the princ iple of the reaction of N aOH w ith pentach lo ropheno l PCP ) and form ation of PCPN a, w aterinso lub le of PCP is transform ed into w aterso lub le salts PCPN a) to realize the extract ion of PCP from the so ils. U ltravio let spectrophotom etric m ethod w as adopted to determ ine PCP at 319 nm. The ex traction cond it ion fo r PCP w as opt mi ized w ith the stirring rate of 300 r /m in, extraction solution at pH 12. 5, the ratio of so il/ liquid= 1/ 8 g /mL) and extract ion tmi e o f 20 m in. The