TiO2离子筛的制备及表征研究.pdfVIP

TiO 离子筛的制备及表征 2 李少鹏，张钦辉，孙淑英，尹先升，于建国∗ （化学工程联合国家重点实验室，华东理工大学，上海 200237, 中国） 摘 要：随着世界锂需求量的日益增长，传统锂矿石提锂的生产方法已经不能满足要求，而以离子筛为关键 材料的卤水提锂技术因其工艺简单、选择性高且环境友好等特点而成为近年来国际上盐湖卤水提锂的重要研 究方向。本文采用商品 TiO + 2(P25)经过改性、浸渍、焙烧、酸洗、干燥等过程得到对Li 具有特殊记忆效应的离 子筛，并通过XRD对样品晶相结构进行了表征；进一步对锂离子的吸附性能进行了研究。实验表明，随着Li/Ti 的增加，前驱体中Li-Ti-O三元体系的量逐渐增加，其中主要物质为立方晶系的Li Ti O ，经酸浸脱得到的 1.33 1.66 4 离子筛为锐钛相TiO2 ，该离子筛对锂离子具有一定的吸附能力。 关键词：TiO ；离子筛；锂；吸附性能；卤水 2 Preparation and Characterization of Titania Ion-sieves * LI Shao-peng, ZHANG Qin-hui, SUN Shu-ying, YIN Xian-sheng, YU Jian-guo (State Key Lab of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China) Abstract: With the increasing requirement of lithium all over the world, the traditional methods of lithium production from pegmatite can not measure up with the environmentalism. Thus, the inorganic oxide ion-seives start to be important materials for selective adsorption of lithium from brine or seawater. In this paper, titania ion-sieves were prepared by impregnation of commercial titania with LiOH solution, calcination and acid treatment to extract the lithium ions. The samples were characterized mainly by XRD and lithium ion adsorption measurement. The results show that with the increase of Li/Ti molar ratio, the Li O-TiO solid solution increased 2 2 and mainly presented the cubic Li Ti O form after acid treat