外文翻译--由 Fe–Mn 的二进制氧化物吸附水中磷酸盐的去除方法.docVIP

Removal of phosphate from water by a Fe–Mn binary oxide adsorbent （由 Fe–Mn 的二进制氧化物吸附水中磷酸盐的去除方法） Abstract Phosphate removal is important in the control of eutrophication of water bodies and adsorption is one of the promising approaches for this purpose. A Fe–Mn binary oxide adsorbent with a Fe/Mn molar ratio of 6:1 for phosphate removal was synthesized by a simultaneous oxidation and coprecipitation process. Laboratory experiments were carried out to investigate adsorption kinetics and equilibrium, in batch mode. The effects of different experimental parameters, namely contact time, initial phosphate concentration, solution pH, and ionic strength on the phosphate adsorption were investigated. The adsorption data were analyzed by both Freundlich and Langmuir isotherm models and the data were well ?t by the Freundlich isotherm model. Kinetic data correlated well with the pseudo-second-order kinetic model, suggesting that the adsorption process might be chemical sorption. The maximal adsorption capacity was 36 mg/g at pH 5.6. The phosphate adsorption was highly pH dependent. The effects of anions such as Cl ; SO?2ˉ, and CO?2﹣on phosphate removal were also investigated. The results suggest that the presence of these ions had no signi?cant effect on phosphate removal. The phosphate removal was mainly achieved by the replacement of surface hydroxyl groups by the phosphate species and formation of inner-sphere surface complexes at the water/oxide interface. In addition, the adsorbed phosphate ions can be effectively desorbed by dilute NaOH solutions. This adsorbent, with large adsorption capacity and high selectivity, is therefore a very promising adsorbent for the removal of phosphate ions from aqueous solutions. 摘要 除磷是重要的水体富营养化的控制和吸附是有前途的方法之一为此目的。Fe–Mn 的二氧化物吸附剂与 Fe/Mn 摩尔比例为 6： 1 除磷被合成一个同时氧化和沉淀的过程。进行了实验室实验调查的吸附动力学和均衡，在批处理模式下。与不同的实验参数的影响即联系时间、 初始磷酸盐浓度、 溶液的 ph 值、 离子强度对磷的吸附进行了调查。由 Freundlich 和朗缪尔等温线模型分析了吸附数据和数据都由 Freundlich 等温线模型井 ?t。动力学数据以及相关的伪二阶动力学模型，暗示吸附过程可能化学吸附。最大的吸附能力是 3