聚酰胺氨基甲酸酯型反渗透复合膜的制备和表征研究.pdfVIP

B109 聚酰胺-氨基甲酸酯型反渗透复合膜 的制备和表征 1 2 2 2 2 周勇 俞三传 金可勇 刘立芬 高从堦 （1.浙江大学材料与化学工程学院，杭州 310027 2. 国家海洋局杭州水处理技术研究开发中心，杭州 310012 ） 摘 要 用 5-氯甲酸酯异酞酰氯（CFIC ）与间苯二胺（MPD ）通过界面聚合技术制备了一种聚 酰胺-氨基甲酸酯型反渗透复合膜。该膜表面活性层经全反射红外差谱分析为聚酰胺-氨基甲酸 酯，既含有酰胺基功能团（-CONH- ）又有氨基甲酸酯功能团（-OCONH- ）；其亲水性优于均苯三 甲酰氯（TMC ）与MPD 通过界面聚合技术制备的聚酰胺。另外，CFIC/MPD 复合膜的水通量及 其对氯化钠的截留率均也大于 TMC/MPD 膜。通过 AFM 和 SEM 观察表明聚酰胺-氨基甲酸酯型 反渗透复合膜的膜面致密，且呈峰谷形。 关键词 PREPARATION AND CHARACTERIZATION OF POLYAMIDE-URETHANE THIN-FILM-COMPOSITE MEMBRANCE 1 2 2 2 2 Zhou Yong ，Yu sanchuan ，Jin Keyong ，Liu Lifeng ，and Gao Congjie (1.College of Material and Chemistry, Zhejiang University, Hangzhou，310027 China；2.The Development Center of Water Treatment Technology，SOA ，Hangzhou ，310012 China) Abstract In this study, Reverse osmosis (RO) membranes with 5-chloroformloxy- isophthaloyl chloride (CFIC) and m-phenylenediamine(MPD) were prepared through interfacial polymerization technique on the polysulphone supporting film. The membranes produced were characterized by permeation experiments with salt water and FTIR ,as well as imaging using atomic force microscopy (AFM) and scanning electronic microscopy (SEM). This study has shown that the active layer of CFIC/MPD TFC membrane is polyamide-urethane, the water adsorption of CFIC/MPD material is higher than that of TMC/MPD material, the flux and rejection of CFIC/MPD TFC membrane is also better than TMC/MPD TFC membrane in the same condition and the surface of CFIC/MPD TFC membrane is compact but not smooth. Keywords 项目：863 高技术研究发展计划（No. 2002AA328010 ）及国家973 计划