弱碱三元复合驱采出液乳化特性研究.DOCVIP

弱碱三元复合驱采出液乳化特性研究 王迪1 贺凤云2 （1,2_东北石油大学） 摘要：为确定弱碱三元驱采出液油水分离工艺及操作参数，进行了弱碱三元驱采出液乳化特性研究，利用电位仪、界面流变仪等仪器测定了采出液乳化程度、双电层电位及界面张力，结果表明弱碱三元采出液乳化状态复杂，呈现多种乳状液共存；乳状液内相颗粒平均粒径基本为4.48-5.5um，且界面膜厚度增加；采出液带电离子的扩散双电层的 Zeta 电位均在-30mV~-50mV之间；采出液界面张力一般0.01~1 mN/m之间 关键词：弱碱三元驱Abstract The emulsifying characteristics research of the produced liquid in weak base alkaline-surfactant-polymer lay the theoretical foundation for the process ofoil-water separation and the choice of operating parameters, this paper mainly researchs the degree of emulsification of produced fluid, the properties of electrostatic double layer and interfacial tension. Studies have shown that the emulsified state of produced fluid is complex, it shows the coexistence of multiple emulsion, the average granul diametre of internal phase in emulsion fluid is 4.48-7um, and the thickness of boundary mask increases until the maximum thickness reachs to 2.5um ~ 3.75um; the Zeta potential in diffuse electric double layer of charged ions is between -30mV ~ -50mV; the boundary mask of produced liquidis always between 0.01 ~ 1 mN / m, less than the oil/water interfacial tension of the produced liquid in strong base alkaline-surfactant-polymer.The stability of emulsion is good, and not conducive to oil-water separation. Keywords: Weak base alkaline-surfactant-polymer Produced fluid emulsify IFT 强碱三元复合驱在大庆油田中区应用较多[1-5]，强碱NaOH的存在，在生产中造成油层结垢堵塞[6-11]，油井卡泵，地面集输管线及处理设备结垢、腐蚀，且采出液处理难度大、成本高[12,13]。为避免这些不利影响，以Na2CO3或NaHCO3代替NaOH即弱碱三元复合驱目前在大庆油田已有应用[14-17]，弱碱三元复合驱采出液界面特性、乳化程度等还没有人进行定量研究，本文针对大庆某弱碱三元驱试验区块进行了采出液乳化特性研究[18]，可为弱碱三元驱采出液油水分离工艺的选择、设备结构优化、处理温度及加药浓度的确定奠定理论基础，有利于弱碱三元驱在油田中的应用。 1.采出液乳化程度 应用PIP9.0型颗粒图像处理仪4-丁20-斜P038 2.85-43.86 13.54um 5.43um 0.490m2/cm3 N4-丁30-P038 2.85-43.86 14.33um 4.48um 0.521m2/cm3 粒度分布及累计颗粒度分布见图1~图4所示。 图1南4-丁20-斜P038井乳化情况 图2 南4-丁20-斜P038井乳状液粒度及累积粒度分布 图3葡70-斜892 水驱采出液乳化情况 图4葡70-斜892井乳状液粒度及累积粒度分布 水驱采出液的乳状液是油包水(W/O)型乳状液，弱碱三元驱采出液，由于含化学剂，采出液乳化状态更加复杂[19]，除含油包水(W/O)、水包油(O/W)外，还含有多重乳状液(O/W/O)，呈现多种乳状液共存。化