聚乙烯木塑阻燃材料.docx

毕 业 设 计（论 文）题目:聚乙烯木塑阻燃材料子题：专业：材料化学指导教师：刘俊龙学生姓名：宋景海班级-学号：材化102-062014年 6 月大连工业大学本科毕业论文聚乙烯木塑阻燃材料Polyethylene wood fire-retardant materials设计（论文）完成日期 2014年 6月3日学院：纺织与材料工程学院专业：材料化学学生姓名：宋景海班级学号：材化102-06指导教师：刘俊龙评阅教师：刘国2014年 6月摘要聚乙烯传统的加工方法是直接加工，其再生成本较低，工艺相对简单。但是制品对环境的污染较大，不利于环保，而且不具有阻燃的效果。为了改善这两方面的缺点，将木粉与聚乙烯混合，其中加入阻燃剂制作聚乙烯木塑阻燃材料。本论文选择十溴二苯乙烷、三氧化二锑和水镁石作为阻燃剂，分别作卤素阻燃、低卤阻燃和无卤阻燃三方面。考察木粉与阻燃剂的添加量对制品的物理性能、阻燃性能等的影响，还做了部分样条的流动性测试、吸水率测试和断面的扫描电镜。结果表明，加入木粉与阻燃剂后，断裂伸长率和冲击强度均降低，由易燃转变为阻燃。聚乙烯是易燃物品，木粉也是易燃物品。加入阻燃剂后，由易燃变为难燃。加入卤素阻燃剂后最高氧指数为27.13%，加入水镁石，最高氧指数为28.83%，加入水镁石与卤素混合阻燃剂，做低卤阻燃，最高氧指数为27.78%。总体看来，三组最高氧指数相差不大，都达到了阻燃的效果。总结得出：聚乙烯与木粉混合可以得到聚乙烯木塑复合材料。在其中加入阻燃剂可以制成阻燃材料。在聚乙烯中加入木粉和阻燃剂后，断裂伸长率和冲击强度都随着添加量的增大而降低；加入水镁石，吸水率降低；加入阻燃剂后的阻燃效果明显。关键词：PE；十溴二苯乙烷；三氧化二锑；水镁石AbstractPolyethylene conventional processing method is direct processing, low cost of regeneration, the process is relatively simple. But the larger environmental pollution products, is not conducive to environmental protection, and do not have fire-retardant effect. To improve the disadvantage of both the wood powder mixed with polyethylene, the polyethylene produced was added wood flame retardant material.Select the paper decabromodiphenylethane, antimony trioxide as a flame retardant and brucite, respectively, for halogen flame retardant, low halogen flame retardant and flame retardant in three areas. Add flour and flame retardant amount examine the impact of product physical properties of flame-retardant properties, but also made ??some kind of mobility testing, water absorption tests and cross-section scanning electron microscopy. The results showed that the wood flour was added and the flame retardants, impact strength and elongation at break decreased by changing the flammable flame. Polyethylene is combustible materials, wood is also flammable. After adding a flame retardant, the flame becomes flammable. After adding halogen flame retardants highest oxygen index of 27.13 percent, adding Brucite maximum oxygen index was 28.83%, adding Bruc