基于Butler方程Al-Mg-Er三元合金表面张力的计算-中国有色金属学报.PDF

20 5 2010 5 Vol.20 No.5 The Chinese Journal of Nonferrous Metals May 2010 1004-0609(2010)05-0930-07 ButlerAl-Mg-Er ( 410083) ButlerCALPHADAl-MgMg-Er Al-ErAl-Mg Mg-ErAl-Er ToopAl-Mg-Er Al-Mg-Er 0.356~0.783 N/m Al-Mg-Er ButlerToop TG146. 1 A Calculation of surface tension of Al-Mg-Er ternary alloy based on Butler’s equation SUN Shun-ping, YI Dan-qing, ZANG Bing (School of Materials Science and Engineering, Central South University, Changsha 410083, China) Abstract: Based on Butler’s equation, the surface tensions of Al-Mg, Mg-Er and Al-Er binary alloys were calculated in combination with thermodynamic data and excess Gibbs energies parameters calculated by CALPHAD technology. The results show that the surface tension of Mg melts increases with the additions of Al and Er. Calculating the excess surface tensions of Al-Mg, Mg-Er and Al-Er binary alloys, the excess surface tensions and excess Gibbs energies have an opposite deviation compared with ideal solution. Choosing Er as the asymmetric component in asymmetric model and combining with Toop model, the surface tension of Al-Mg-Er ternary alloy were calculated. The results indicate that the surface tension of Al-Mg-Er ternary alloy is approximately in the range of 0.356−0.783 N/m, and the surface tension increases with increasing the addition of Er element. Key words: Al-Mg-Er ternary alloy; surface tension; Butler’s equation; Toop model [1] [1] TANAKA[2]Bi-Sn QIAO[3]