HNMR核磁共振.pptVIP

Chapter 12 Nuclear Magnetic Resonance Spectroscopy;Introduction;Nuclear Spin;External Magnetic Field;Two Energy States;?E and Magnet Strength;1st question: ?E = h? = ? h B0 2? ;Magnetic Shielding;Shielded Protons;Protons in a Molecule;NMR Signals;Problem 2;The NMR Spectrometer;The NMR Graph; Tetramethylsilane;Chemical Shift;Delta Scale;Problem 3;Location of Signals;Typical Values;Poblem 4;Aromatic Protons, ?7-?8;Porphyrin;Vinyl Protons, ?5-?6;Acetylenic Protons, ?2.5;Aldehyde Proton, ?9-?10;O-H and N-H Signals;Carboxylic Acid Proton, ?10+;Number of Signals;Intensity of Signals;How Many Hydrogens?;Spin-Spin Splitting;1,1,2-Tribromoethane;Doublet: 1 Adjacent Proton;Triplet: 2 Adjacent Protons;The N + 1 Rule;Range of Magnetic Coupling;Splitting for Ethyl Groups;Splitting for Isopropyl Groups;Coupling Constants;Values for Coupling Constants;Complex Splitting;Splitting Tree;Spectrum for Styrene;Stereochemical Nonequivalence;Some Nonequivalent Protons;Time Dependence;Hydroxyl Proton;N-H Proton;Identifying the O-H or N-H Peak;Problem 5;Carbon-13;H and C Chemical Shifts;Combined 13C and 1H Spectra;Differences in 13C Technique;Spin-Spin Splitting;Proton Spin Decoupling;Off-Resonance Decoupling; Interpreting 13C NMR; Two 13C NMR Spectra;MRI;End of Chapter 12