多孔阵列微结构设备内液－液两相流BaSO4纳米颗粒可控制备的研讨.pdfVIP

多孔阵列微结构设备内液－液两相流BaSO 纳米颗粒可控制备的研究 4 李少伟,徐建鸿, 王玉军，骆广生 (清华大学化学工程联合国家重点实验室，北京100084) 摘要：本文在前期单通道液－液分散流纳米颗粒制备工作的基础上，发展了多孔阵列分散液－液两相流纳米颗粒制备的 新设备，以BaCl 的水溶液和H SO 的正丁醇溶液为反应体系，研究了体系内两相流动的基本规律，进而考查了流动和 2 2 4 传质情况对纳米颗粒制备的影响。实验以油相（正丁醇溶液）为连续相，水相为分散相，在体系内形成了尺寸可控的液 滴流和饼状流，实现了纳米颗粒的可控制备，所得颗粒尺寸在10 到30nm 。考查了传质与反应对界面张力和流型的影响 规律，进而研究了流型对颗粒尺寸的影响。结果表明，传质和反应量的增大会引起界面张力的减小，从而使流动从饼状 流向液滴流转变。对于液滴流和饼状流两种情况，均有颗粒尺寸随液滴尺寸的增大而减小。 关键词：多孔分散，纳米颗粒，液滴，混合，微结构 中图分类号：TQ051.83; TQ051.893 文献标识码：A Controllable production of BaSO nanoparticles by liquid-liquid two-phase 4 flow in a pore array microstructrued device Shaowei Li, Jianhong Xu, Yujun Wang, Guangsheng Luo (The State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China) Abstract: The paper presents the characteristics of a well controlled liquid-liquid two-phase flow in a pore array microstructured device. A system of H SO and BaCl respectively in two phases to 2 4 2 form BaSO4 nanoparticles was used as a probe to characterize the micro-scale two-phase flow, interphase mass transport and chemical reaction in the microflow process. Nanoparticles with small size and good dispersibility were produced through drop or disk flows in the microstructured devices. The influence of mass transfer and chemical reaction on interfacial tension and flow patterns was discussed based on the experiments. Meanwhile the effect of the two phase flow patterns on the nanoparticle size was discussed. It was found that the increase