基于观测的臭氧污染研究方法.PDFVIP

地 球 环 境 学 报 专 论 JEE Vol.8 No.6 ǀ Dec. 2017 REVIEW Journal of Earth Environment DOI: 10.7515/JEE201706001 基于观测的臭氧污染研究方法 吴  琳，薛丽坤，王文兴 山东大学环境研究院，济南 250100 摘  要：总结了国内外研究中常用的基于外场观测的臭氧污染成因分析方法。区域传输和本地生成的相 对贡献以及臭氧与前体物的非线性关系是研究臭氧污染和制定控制对策的两个关键科学问题。基于对观 测数据的分析，常见的量化区域传输和本地生成贡献的方法包括背景点测量法、TCEQ 区域背景臭氧估 算法和主成分分析区域背景臭氧估算法；用于诊断臭氧光化学生成机制的方法包括光化学指示剂比值法 和基于观测的化学模型。本文对上述方法的原理和应用情况进行了总结，并对其优缺点和适用条件进行 了评述，以期为环境监测资料的深入科学分析提供参考和借鉴。 关键词：臭氧污染；外场观测；区域背景臭氧；臭氧前体物关系；光化学指示剂；臭氧生成效率；基于         观测的模型；空气质量监测 Review on the observation-based methods for ozone air pollution research WU Lin, XUE Likun, WANG Wenxing Environment Research Institute, Shandong University, Jinan 250100, China Abstract: Background, aim, and scope Ozone (O ) is among the most important trace gases in the atmosphere. It 3 plays a central role in the tropospheric chemistry as a major precursor of the hydroxyl radial, and is also a potent greenhouse gas and an important air pollutant. In the troposphere, ozone is mainly produced by photochemical reactions of nitrogen oxides (NO ) and volatile organic compounds (VOCs) in the presence of sunlight. Ozone x air pollution was first recognized in the Los Angles smog in 1950s, and has since then become a major challenge of air quality management in developed countries. It is fundamental to quantify the relative contributions of both regional transport and local production and to diagnose the non-linear O -precursor relationships, to formulate 3 the science-based control strategies. For decades, a large body of research has been conducted worldwide to understand the ozone pollution, from which dozens of effective methods based o