高岭土制备聚合氯化铝净水剂工艺参数的优化-哈尔滨理工大学学报.PDF

16 2 V o l16 N o2 2011 4 JOURNA L O F HAR BIN UN IVER SITY OF SCIENCE AND TE CHNOLOGY A pr. 2011 孔秀琴, 刘 畅, 兰建伟 ( , 30050) : 以高岭土为原料, 经活化预处理- 酸溶- 过滤- 浓缩- 聚合- pH 调整等工序, 制备液 体聚合氯化 ( PAC ) 净水剂; 通过正交设计对这一新的制备方法进行工艺优化试验. 结果表明: 用 高岭土制备 PAC 的工艺参数中, 对于产品质量的影响程度依次为: 酸溶酸料比 预处理物料比 焙烧温度 酸溶温度 酸溶时间 焙烧时间; 用高岭土制备 PAC 的理想工艺参数为: 预处理物料 比为 26g /m l( 土/处理液), 焙烧温度为 00 , 焙烧时间为 15h, 酸溶时间为 2h, 酸溶酸料比为 40m l/ g(酸 /土) , 酸溶温度为 85 . : 高岭土; 制备; 聚合氯化 ; 工艺优化 : TQ 1109 : A : 100 - 26 83( 2011) 02- 0122- 0 Opt im ization of P repa ring Po lya lum inium C hlo ride from Kao lin K ONG X iu qin, LIU Chang, LAN J ianw ei ( P etrochem ical Engineering, G ansu U n iversity of T echnology, Lan zhou 30050, C h ina) Abstract: A process for preparing liquid po lyalum in ium ch loride coagu lant is introduced. It u ses kaolin as raw m ateria,l w hich is pretreated, and then roasted, soaked in hydrochloric acid, f iltrated, concentrated, m ixed for po lym erization and fina lly adjusted for pH. W e optmi ize the process by m eans of orthogona l text m ethod. T he re su lts show that the order of influence degree of the product quality from b ig to sm all is: aciddissolution feedstock rat io, the propo rtion of pretreated w ith hydroch lo ric acid, roasting tem perature, acid d isso lv ing temperature, ac id disso lv ing tmi e and roasting t mi e. The appropriate cond itions of produc ing PAC from kao lin are as fo llow s: the pro portion of pretreated w ith hydrochloric acid is 26; roasted at 00 fo r 15h; then hydroch loric ac id is mi m ersed