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Advances in Environmental Protection 环境保护前沿, 2017, 7(6), 476-483
Published Online December 2017 in Hans. /journal/aep
/10.12677/aep.2017.76061
Effects of Humic Acid on Aqueous
Physicochemical Properties and Ecological
Toxicity of Nano-Zirconium Oxide
1,2 2 2 1,2 1,2 1,2*
Se Wang , Zhirao Li , Shuwen Wang , Hao Fang , Ding Zhu , Zhuang Wang
1
Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Nanjing
University of Information Science and Technology, Nanjing Jiangsu
2
School of Environmental Science and Engineering, Nanjing University of Information Science and Technology,
Nanjing Jiangsu
nd th th
Received: Nov. 22 , 2017; accepted: Dec. 6 , 2017; published: Dec. 13 , 2017
Abstract
Humic acid (HA), ubiquitous in natural water, can interact with engineered nanomaterials (ENMs),
but studies on HA affecting on aquatic behavior and ecological toxicity of nano-zirconium oxide
(nZrO2) are still limited. Herein, we investigated the effects of a HA analogy on the physicochemi-
cal properties of nZrO2 and growth inhibition toxicity to freshwater algae. Results show that in-
creasing the mass concentration of HA decreased the zeta potentials and hydrodynamic diameters,
implying that HA significantly enhanced the dispersion stability of nZrO2 in the aquatic media. It
was also found that the mass concentration of HA was higher, the stability extent was greater. This
process was independent on the time of settling. Furthermore, increasing the mass concentration
of HA increased the growth inhibition toxicity of nZ
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