沸石分子筛催化桥式四氢双环戊二烯异构制备挂式四氢双还戊二烯研讨.pdfVIP

沸石分子筛催化桥式四氢双环戊二烯异构制备挂式四 氢双还戊二烯研究 * 邹吉军，张香文 ，邢恩会，王 莅，米镇涛 (天津大学化工学院，绿色合成与转化教育部重点实验室，天津300072) 摘 要: 挂式四氢双环戊二烯是重要的高能量密度液体燃料，对于提高飞行器性能具有重要意义。挂式双环 戊二烯通过桥式双环戊二烯异构反应制得，一般采用对环境污染的AlCl3作为异构催化剂。本课题采用分子筛 催化剂取代AlCl3 ，探索绿色环保的异构新工艺，对分子筛筛选、表面酸性调节、反应条件优化和催化剂再生 进行了研究。研究表明：具有较大孔径的HY分子筛具有较高的活性，具有较多弱酸性中心的HUSY活性比HSSY 高，负载F元素可以抑制强酸位和中强酸位、增加弱酸位，提高反应选择性。F的最佳负载量为6.6 % ，反应最 佳温度为 195 °C，最佳催化剂浓度为20 % ，高温焙烧可以使催化剂再生而不影响活性。 关键词: 桥式双环戊二烯；挂式双环戊二烯；分子筛；异构化；F 改性 Zeolite Catalytic Isomerization of Endo-THDCPD to Exo-THDCPD ZOU Ji-jun, ZHANG Xiang-wen*, WANG Li, MI Zhen-tao (Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China) Abstract: Exo-THDCPD is an important high energy density fuel that can promote the performance of aircrafts. Exo-THDCPD is generally produced from the isomerization of endo-THDCPD with environmentally unsafe AlCl as catalysts. In this work, zeolites 3 were used to replace AlCl3 to catalyze the isomerization of endo-THDCPD, with the aim to explore a green technology for the production of exo-THDCPD. The evaluation 收稿日期：2006-08-20 作者简介：邹吉军，1978 年生，讲师，E-mail ：jj_zou@ of serious zeolites, modification of acidity, optimization of reaction conditions, and the regeneration of deactivated catalysts were investigated. HY zeolites with large pore size are effective for the isomerization reaction. HUSY is more active than HSSY due to its weak acidic centers. F-modification can decrease the strong acidic and medium acidic centers but increases the weak acidic sites. As a result, the selectivity of exo-THDCPD is enhanced. The optimal reaction conditions are as following: amount of F as 6.6 %, reaction temperature as 195 °C, amou