重油催化裂化装置清洁汽油生产工艺及催化剂的工业应用研究—硕士.docVIP

重油催化裂化装置清洁汽油生产工艺及催化剂的工业应用研究 摘 要 汽油是我国最重要的动力燃料之一。近年来，由于人们环保意识的增强以及各种环境保护法规要求的日趋严格，对燃料油产品的质量提出了较高的要求，特别是汽油中的烯烃含量。催化裂化汽油烯烃含量高，是汽油中烯烃的主要来源，因此降低催化裂化汽油中的烯烃含量，是我国生产清洁汽油的关键。 20年2011年松原石化为使出厂汽油中的烯烃含量满足GB17930-2006达到30%（V）以下的标准要求在其万吨/年重油催化裂化装置上进行了降烯烃催化剂DOCO的工业应用。工业应用试验研究详细考察了DOCO催化剂及MIP技术各种工艺操作参数（反应温度、剂油比、汽油馏程等）对降低催化裂化汽油烯烃的影响规律结果表明，催化剂，汽油中烯烃体积含量11个百分点汽油研究法辛烷值保持不变柴油十六烷值降低幅度不大汽油、柴油和液化石油气总的液体产品收率略有提高降低反应温度、提高剂油比及催化剂活性提高汽油馏程均可起到降低稳定汽油中烯烃含量的作用。MIP工艺技术改造和DOCO催化剂应用能够保证现有加工流程汽油柴油产品出厂，标致MIP工艺技术改造和DOCO催化剂应用取得成功。 关键词： 催化裂化清洁汽油，工艺技术，催化剂，降烯烃，工业试验  Commercial Application investigation of the cleaning gasline productive technology and Catalyst in the Heavy Oil FCC UNIT ABSTRACT Gasoline is one of the most important power fuel in our country. In the recent years, with the increasing strictness of environment protection, the demand to olefin content of gasoline is becoming higher and higher. Olefin content of gasoline mainly come from catalytic cracking gasoline, hence, it is a key to reduce the olefin content of catalytic cracking gasoline for clean gasoline production. From 2010 to 2011, in order to make gasoline to reach the GB17930-1999 standard which the olefin content is under 35%(v), The Qianguo petrochemical company carryed out the commercial application investigation of the reducing olefin DOCO catalyst testing and MIP technical updating in the 35×104 FCC unit. The commercial application investigation inspected the influence regular pattern of all kinds of the operation parameter for the DOCO catalyst and MIP (reaction temperature, catalyst/oil ratio, the gasoline boiling range) to the olefin content of gasoline in the test. The result of the commercial application investigation shows that there are well effects after the catalast application and the MIP update and through the adjust and data fumble, the main shows is that the olefin content in gasoline reduced above 11 percent point and it is controlled and adjustable; the RON of gasoling kept in 91 and unchanged; the cetane numb