电镀黑铬太阳能选择性吸收器的热稳定性及耐蚀性.pdfVIP

VoII．28 No．8 【电镀 】 Thermalstabili andc0rr0si0nresistance0felectr0plated blackchr0mium s0larselectiveabs0IIber M ．R．Bayati，一，K．Janghorban ，M ．H．Sh撕 at (1．D印amnentofMetallu唱icalandMaterialsEngiIlee g，IranUniVers时 ofScienceandTechnology，Tehran，Iran； 2．D印artrI1emofMateria1sScienceandEngineering，Schoo1ofEng eering，Sh zuniVersit)r，Shiraz，I啪 ) Abstract：BlackchromiumisoneOfthemostat仃activesolaf 黑铬镀层作为对比。根据 lSo／CDl2592．2标准，评价了热处理 selectiveabsorberspassed12lboratOIy experimentsand has 循环前后镀层的太阳能吸收／发射性能和热稳定性。分别采用扫 practicallybeenused sOlarmem alcollectOrs．Theaim Of 描电镜和x射线衍射 ，表征 了镀层的微观结构和化学组成。采 tl1isresearchistoevaluatememenTlalst￡lbilitVandconl0siOn 用分光光度法测量了镀层的吸收率和发射率。结果表明，镀液 resistanceOfblackchr0mium sOlarselectiveabsOrbers．Black 中的配位剂对镀层的热稳定性有显著影响。与六价铬镀层相比， chr0mium layerswere elec仃oplated on coppersubs仃ates 三价铬镀层具有更优异的热稳定性和耐蚀性。 Om abathcontainingtrivalentandhexavalentchr0mium 关键词：黑铬；电镀；太阳能吸收器；选择性；耐久性 ions，respectively．Solar absor1)tiOn and emission were measured by spectrophotom咖 r bef0lre and after heat l Intr0ductiOn 仃eatn1entcyclesandtllethe咖 als切bilityofthedepOsited layerswasevaIuatedaccOrdingt0ISO／CD 12592．2standard． In ph0t0mem alsOlar energy conVersion，the most Scanningelec仃onmicroscopy(SEM)andX-raydi衢action importantaIldcriticalpartoftheso1arco1lectoristhe (×RI)) tec}u1iques were emp1oyed to characterize ￡lbsOrbersum cewhich shOuld absOrb maximum sOlar micr0stn1cture and chemicalcomposition of the lavers， radiationandconvertitintoheat【¨ ． Thecostandeffective respectiVely．Itwasf0und tl1atcomplexing agentin the