聚合物加工过程中的形态演变和化学反应形态演变.pptVIP

REACTIVE POLYMER BLENDINGFROM FUNDAMENTALS TO APPLICATIONS Morphology formation starting from polymer pellets? Underlying chemistry of compatibilization 1. Functionalization of PP: 2. Interfacial reaction between PP-g-GMA and PBT-COOH: GMA: n:一条分子链上的平均GMA数量 One-step reactive blending Two-step reactive blending: Step 1: Functionalization Step 2: Reactive compatibilization One-step reactive blending : 2 to 1: functionalization + compatibilization Two-step reactive blending PP/PA6 Step 1: Functionalization of PP Step 2: Reactive compatibilization One-step reactive blending a b DV2 DV1 One-step reactive blending VS. Two-step reactive blending One-step reactive blending for PP/PBT blends Process optimization: devolatilization PP/PBT = 70/30 A1 A3 A2 * 1. Initial stage of morphology formation 2. Copolymer formation under mixing 3. Morphology development of reactive blends in screw extruders 4. One-step reactive blending 5. Nano-materials Outline Pellets of 1 to 3 mm Particles of 0.1 to 10 μm Under classical thermomechanical conditions, the morphology development is a very rapid process and is accomplished in less than 2 minutes. How does the morphology develop? Melting/plastification Stretching Break-up Coalescence Kinetic model for the morphology development melting dispersion Four secenarios rate of melting rate of dispersion (deformation + break-up) rate of stabilisation (or without coalescence); rate of melting rate of dispersion with coalescence; rate of melting ~ rate of dispersion with coalescence; rate of melting rate of dispersion with coalescence. PP/PA6 non-compatibilized blends vs. PP/PP-g-PA6/PA6 compatibilized blends 0.5% PA6 With dilute systems ( 1%), the particles formed in the very early stage of melt blending are very small. They do not change in size when a copolymer is present. Otherwise they grow in size. This shows that coalescence take place in very dilute blend systems and that the presence of a copolymer