recovery of cooking chemicals 化学法制浆课件.pdfVIP

Lecture-5# Recovery of cooking chemicals Outline • Overview of process • Evaporation • Combustion • Causticizing Overview of process Compositions of black liquor  Black liquor consists of various organic components, small amounts of inorganic dissolved from the wood, some inorganic compounds (the white liquor) and water.  The composition of the white liquor may vary slightly between different pulp mills.  The organic compounds consist mainly of sodium salts of dissolved lignin and dissolved and degraded carbohydrates. Chips NaOH Inorganics (g/kg) Na S Digester Pulp NaOH (75-100) 2 Na S (30-60) 2 Na CO (20-45) Black Liquor 2 3 Na SO (1-15) 2 4 Na S O (1-10) 14-18% Solids 2 2 3 NaCl (1-10) pH 12 65% Organics 35% Inorganics Physical and thermodynamic properties  The properties of black liquor, both chemical and physical are of outmost importance in the design of the evaporation plant, condensate treatment plant and recovery boiler.  Summary of the most important properties and their importance Property Importance Density To obtain correct mass balances. Density is also an indication of