大气颗粒物化学组成分析精选.pdfVIP

19 10 化 学 进 展 Vol. 19 No. 10 2007 10 PROGRESS IN CHEMISTRY Oct. , 2007 大气颗粒物化学组成分析* 刘永春 贺 泓* * ( 中国科学院生态环境研究中心 环境化学与生态毒理学国家重点实验室 100085) 大气颗粒 的化学组成非常复杂, 其中包括大量矿质氧化 可溶性硫酸盐硝酸盐海盐多 环芳烃有机酸和有机氯等大气颗粒 对局地区域甚至全球大气辐射平衡大气能见度和元素的生 化 学循环具有重要影响, 危害人体健康并参与大气非均相反应化学组成是决定大气颗粒 各种环境效应的 关键因素国内外对大气颗粒 化学组成分析进行了大量的研究工作, 本文对此进行了综述随着气动力 学透镜的发展与应用, 结合快速灵敏的光谱和质谱检测手段, 适合大气颗粒 化学组成的在线分析方法取 得了较大的突破 大气颗粒 化学组成 分析方法 : X 13111 O659 : A : 1005- 281X( 2007) 10- 1620- 12 Analysis of Chemical Composition of Atmospheric Particles * * Liu Yongchun H e H ong ( State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco- Environmental Science, Chinese Academy of Sciences, Beijing 100085 , China) Abstract There has been int ense interest in atmospheric particulates because of their important environmental effects su ch as the effect on radiant balance, degradation of visibility, biochemical cycle of elements, human health and heterogeneous reaction in atmosphere. Chemical composition is a crucial factor for the environmental effects of atmospheric part iculates. The online analysis methods for atmospheric particles have made a great progress w ith the development of aerodynamic lens, spectrometer and mass spectrograph which has high time resolution and low detect limit . The chemical composition of atmospheric part icles is very complicated. It consists of mineral oxides, soluble sulfate and nitrate, sea salt, polycyclic aromat ic hydrocarbons ( PAHs) , organic acids and organochlorines and so on. The research