质谱在钢铁行业过程控制中快速气体分析的应用.docVIP

Applications of?Fast Gas Analysis by Mass Spectrometry?to Process Control in the Iron and Steel Industry 质谱在钢铁行业过程控制中快速气体分析的应用 Robert Wright Thermo Electron Corporation Abstract 摘要 This paper describes how?fast on-line gas analysis by mass spectrometry is used in the iron and steel industry to optimise various processes, based on accurate and complete analysis. Steel making gas analysis is used for?better process control and end-point determination to expedite process-turnaround. Iron making gas analysis is used to operate more efficiently and safely. Coke oven gas analysis is used to optimise the gas cleaning.??Waste gases from various?processes are used as fuel gas,?which needs to be characterised in terms of calorific value, Wobbe index and stoichiometric air requirement, but?these gases have fast changing composition. These gases are also mixed to make mixed fuel gas. Fast complete gas analysis is required to optimise the mixing of these gases to provide?mixed gas of?constant calorific value (or Wobbe Index). 本文描述在钢铁行业中如何采用质谱对气体进行准确、完整的快速在线气体分析以优化不同的过程。炼钢过程中的气体分析用于更好地控制过程，确定吹炼终点以加速吹炼周期。焦炉中的气体分析用于优化气体纯化。来源于不同过程中的废气用作燃气，通过热值，华比值和按化学计量组成所需空气量表征，这些气体组成变化很快。这些气体也被混合形成混合燃气。因此采用快速全面的气体分析来优化混合过程以提供稳定华比值的混合气体。 Introduction介绍 The type of mass spectrometer used for on-line gas analysis is commonly referred to as a process mass spectrometer, or PMS. One of the world’s largest scientific instrument manufacturers, Thermo Electron Corporation, has been manufacturing process mass spectrometers for over 20 years with more than 1000 systems installed world-wide on a wide range of applications – in the chemical and petrochemical industries and in biotechnology and for research development, as well as iron and steel. Specifically for the iron and steel industry during the past 15 years, Thermo Electron has installed over 100 mass spectrometers for gas analysis applications involving the following plants: coke ovens, blast furnace (BF), direct reduction iron (DRI), basic oxygen