PC2_Lesson_3 瑞士洛桑高工《光化学 II》课件.pdf

7.4 Examples of homogeneous and nano-heterogeneous systems A. Photo-oxydation of aromatic hydrocarbons by acrdinium dyes Cl N + N + N + CH3 CH3 SO3– MA+ CMA+ APS0 τ [ns] Φ –  Dye f φ(S/S ) [V/ SHE] ∆E0,0 [eV] + 42 10-methyl-acridinium (MA ) 0.71 – 0.184 2.66 + 9-chloro, 10-methyl-acridinium (CMA ) 40 0.68 – 0.027 2.71 0 10-acridinium-3-propylsulfonate (APS ) 36 0.65 – 0.350 2.74 ket ksep + M 1 – + – + – + (S + D) ( S* + D) (S / D ) S + D S + D + M k–et 40 Photo-oxydation of aromatic hydrocarbons by acrdinium dyes The quantum yield ΦM+ for the production The separation rate constant ksep was of the radical cation monitor M+ is measured separately and was found to be measured by ns laser transient absorption independent of the donor D : spectroscopy (laser flash photolysis).