Summary of Chemical Reaction Engineering 化学反应工程 教学课件.ppt

Summary of Chemical Reaction Engineering Furthermore, for reactant A of a constant-volume system: Chapter 2 Kinetics of Homogeneous Reactions The rate constant of reaction k : Arrhenius’ Law: For varying-volume system Three ideal reactors: Batch reactor (BR, unsteady-state operation) Plug flow reactor (PFR, steady-state flow) Mixed flow reactor (MFR, steady-state flow) The related time concepts about a reactor : Space time ? , holding time (or mean residence time) , reaction time t . Usually, For the constant-density system, The optimum reactor design for single reactions General rule of comparing a single PFR with a single MFR: Performance Equation: Quantitative Calculation: The definition of the instantaneous and the overall fractional yield of R, Irreversible Series-Parallel Reactions Irreversible Series-Parallel Reactions Irreversible series-parallel reactions can be analyzed in terms of their constituent (组成的) series reactions and parallel reactions in that optimum contacting for favorable product distribution is the same as for the constituent reactions. For single reactions, the optimum temperature progressions are: The definition of E (Residence time distribution, RTD): E(t) dt ＝ dN / N 1. 活塞流模型 The model parameter: dispersion number D/uL For the closed vessel, For the irreversible first-order reaction, The model parameter: N － the number of tanks For the closed vessel, For the irreversible first-order reaction, Thanks for your attention ! 化 学 反 应 工 程 化 学 反 应 工 程 For PFR: For MFR: 化 学 反 应 工 程 How to obtain the maximum concentration of the desired product R ? 化 学 反 应 工 程 化 学 反 应 工 程 Chapter 8 Potpourri of Multiple Reactions Qualitative Discussion (A ? R ? S): For irreversible reactions in series the mixing of fluid of different composition is the key to the formation of intermediate. The maximum possible amount of any and all intermediates is obtained if fluids of different compositions and at different st