有机电致发光器件简介.pptVIP

电子/空穴 复合形成 singlet and triplet 激子 Heavy metal facilitated triplet emission Strong spin-orbit-coupling mixes singlet and triplet MLCT states, M = Ir, Pt, Os, Re, etc. MLCT = metal to ligand charge transfer, LC = ligand centered Organometallic Ir Phosphor External quantum efficiency of Ir(ppy)3 in CBP External quantum efficiency of Ir(ppy)3 in CBP 实验过程 400 ? NPD 200 ? Ir(ppy)3 in CBP 60? BCP 200 ? Alq3 ITO MgAg exciton formation region Ir(ppy)3 short lifetime: 500ns in CBP no fluorescence observed, only phosphorescence (fPL = 0.4) Iridium ? strong intersystem crossing R.J. Watts, et. al