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污泥炭吸附剂对气态汞的吸附 Adsorption of Gaseous Mercury on Sludge Carbon Adsorbent
化 丁 环 保
EN、,IRONMENTAL CHEMICALINDUSTRY ·217·
2012年第32卷第3期 PROTECTl0NOF
污泥炭吸附剂对气态汞的吸附
方平,岑超平,唐子君,唐志雄,陈定盛
(环境保护部华南环境科学研究所,广东广州510655)
[摘要]在同定床反应器上研究污泥炭吸附剂对气态汞(Hgo(g))的吸附特性,并对其吸附机理进行探讨。实验
结果表明:污泥炭吸附剂对H矿(g)的吸附容量随着吸附温度的升高、气体流量的增大而降低,随着Hgo(g)质量
lJmin时,污泥炭吸附剂
浓度的增加而增大;在吸附温度为130℃、Hgo(g)质量浓度为65.2.g/m3、气体流量为l
对H矿(g)的吸附容量达到81.8.g/g,优于选定的商品活性炭。污泥炭吸附剂对Hr(g)的吸附机理主要包括物理
吸附、化学吸附、化学反应以及i者相结合的共同作用。
[关键词】污泥炭吸附剂;汞;吸附容量;吸附机理;废气处理
[文献标识码]A[文章编号]1006—1878(2012)03—0217—05
[中图分类号]X703
ofGaseous on CarbonAdsorbent
Adsorption MercurySludge
FangPing,CenChaoping,TangZijun,TangZhixiong,ChenDingsheng
(SouthChinaInstituteofEnvkonmental 510655,China)
Sciences,MinistryofEnvironmentalProtection,GuangzhouGuangdong
Abstract:The and mechanismof
adsorptionpropertyadsorption gaseousmercury(Hg”(g))onsludge
fixbed resultsindicate
carbonadsorbentwerestudiedina reactor.The that:T1le
experimental adsorption
of carbonadsorbentto withthe of and
sludge Hg”(g)decreasesinereasingadsorptiontemperature
capacity
flowandincreaseswiththe of the
concentration;Whenadsorptiontemperature
gas increasingrig”(g)mass
1 concentrationis65.2 andthe flowisl
is 30℃,the rtg/m3 L/min,theadsorption
Hgo(g)mass gas capacity
to reach81.8 isbeaerthanthecommercialactiva
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