以不同水萃取条件进行MSWI飞灰离子释出之探讨-联合大学.PDFVIP

組別:▓實作組□設計組 理工學院優秀專題競賽論文   以不同水萃取條件進行MSWI飛灰離子釋出之探討 Ion release detections for MSWI fly ash at different water extraction conditions *鍾政宏 李鴻璋 國立聯合大學環境與安全衛生工程學系 摘要 本研究以國內某垃圾焚化（MSWI ）飛灰為對象，探討不同水萃取液固比條件對飛灰中離子釋出 之影響及相關之變化。飛灰經 TCLP檢測， Pb溶出值為 10.3 ±1.4 mg/L ，超過法規標準值(5 mg/L)， 故為有害事業廢棄物。本研究在不同液固比（ L/S = 2 、5 、10）下，以600 rpm攪拌速率，進行 5 分 鐘水萃取飛灰實驗。結果顯示水萃取後飛灰之 Cl 離子可快速釋出，且亦可溶出飛灰大量 Pb 及部分 Cd ，檢測水萃取後飛灰Cd 、Pb總量略有上升，然而除了 L/S = 10 之 Pb略高於 TCLP 法規標準外， 其餘溶出值均已低於法規標準，此亦顯示降低飛灰水萃取之液固比，可兼顧飛灰有害之 Pb 有效釋出 及處理後飛灰符合 TCLP 法規標準。此外，水萃取後飛灰氯含量降至約 8% ，本研究成果可作為探討 MSWI飛灰特性、萃取再利用之參考。 關鍵字：飛灰、水萃取、離子、重金屬、釋出 Abstract A municipal solid waste incineration (MSWI) fly ash was sampled and extracted by water at different liquid/solid (L/S) ratio to detect the varieties of ions release condition. The MSWI fly ash was identified as industrial hazardous waste since its Pb leaching concentration ( 10.3 ±1.4 mg/L) exceeded regulatory limit of 5 mg/L. Water extraction experiments for MSWI fly ash at L/S = 2, 5, and 10 were employed at 600 rpm stirring speed for 5 minutes. The results show that chloride ion quickly released from MSWI fly ash, and much of Pb and few of Cd also dissolved. After water extraction, total Cd and Pb contents in MSWI fly ash slightly increased; nevertheless, metal concentrations were below TCLP limits except L/S = 10 for Pb. In brief, low L/S ratio benefits effective dissolution of hazardous Pb and pass of regulatory TCLP test. Finally, chloride content in the extracted MSWI fly ash was 8% and all the results can be provided as reference for relative researches, including characteristics, extraction and reuse of MSWI fly ash. Keywords: Fly ash; Water extraction; Ion; Heavy m