废弃线路板分离富集金属和非金属的方法研究.DOCVIP

废弃线路板分离富集金属和非金属的方 法研宄 江勇谢厘衛卢彦越廖安平马齐佳谢清若 广西民族大学化学化工学院广西高校化学与生物转 广西城投广庆环保有限公 a广西科技经济开发中心 采用万能高速粉碎机对废弃线路板进行破碎，采用TCP-AES分析线路板中主要 金属含景，研究破碎累积时间对破碎产物以及金属铜在各粒径范围分布的影响， 讨论粉末粒径大小对水力摇床分选效果的影响。结果表明，线路板中金属铜的含 量达约25%;当破碎累积时间为180 s时，得到的破碎产品在0. 151 mm粒径范围 内的产率最高。采用水力摇床分选时，在0. 15l mm粒社的粉末比较适合水力摇 床分选，此粒级中铜的冋收率达到98. 3%以上。 关键词： 废弃线路板;分离富集;金属铜;回收率; 基金：广西科技开发计划项目（桂科攻1355003-1） Study on Separation and Enrichment of Metal and Non-metal of Waste Printed Circuit Board JIANG Yong HE Yuheng LU Yanyue LIAO Anping MA Qijia XIE Qingruo Guangxi Colleges and Universities Key Laboratory of Chemical and Biological Transformation Process Technology， College of Chemistry and Chemical Engneering， Guangxi University for Nationalities; Guangqing Enviroment Protection Technology Co.，Ltd. ; Guangxi Science Technology Economy Development Centre; Abstract： The waste printed circuit boards were crushed with a micro crusher. The mainly metal content in the circuit board is analyzed by using ICP-AES, the research has been conducted about the influence of broken accumulated time on the distribution of broken products and copper which is major metal in different particle size range. The influence of particle size on the hydraulic shaking table separation effect has been discussed. The results indicate that the content of copper in the circuit board is about 25%, the highest yield of the product in the particle size range 0. 15-1 mm was obtained when the accumulated time was 180 s. The powder with 0. 15-1 mm particle size is suitable for hydraulic shaking table separation. The recovery ratio of copper reach above 98. 3% during this range using shaking table separator. Keyword： waste circuit board; separation and enrichment; copper; recovery ratio; 随着电子产业的迅速发展，电子产品的更新换代周期不断缩短。由此产生了大量 的电子废弃物［1-2］。线路板广泛存在于电子产品中［3］,负责各元件之间的内部 电路连接。因此废弃线路板也是电子废弃物中重要的组成部分，成为电子废弃物 的主要来源之一以1。据文献统计，废弃线路板约占电子垃圾总量的4%边1。如 何科学、合理地处理这些废弃线路板对环境保护有重要的意义。 废弃线路板主要由高分子聚合物、树脂、玻璃纤维或荠?十?皮纸和多种金属成分组 成M。线路板脱去元器件后，剩下的是线路板基板。线路板基板中约30%是金 属，约70%是非金属。常见的主要金属有