攀钢低钒铁水选择性氧化的热力学计算.doc

摘要 钒是重要的战略资源，其应用十分广泛。我国是钒资源大国,先天的资源优势奠定了坚实的物质基础,因此，在我国大力开发提钒技术、深加工产品和新应用具有独特的基础和广泛的前景。目前，随着高炉一转炉流程工艺的优化，高炉配加钒钛矿的比例有所降低，导致铁水中钒含量降低，对转炉提钒提出了更高的要求，因此创新提钒方法，优化流程工艺和提高提钒技术水平，对于攀西资源的综合利用具有战略意义。 本课题在了解，掌握攀钢铁水条件，如温度，氧化剂等对铁水提钒的影响的基础上，学习了铁水提钒原理。利用FactSage以及Origin软件研究攀钢低钒铁水的V、P选择性氧化问题。计算了低钒铁水提钒的转化温度，氧化剂的选择问题及温度的影响。得出铁水中钒的选择性氧化实验选定合适的氧化剂为CO2，并计算提钒的转化温度为1361℃，绘制了低钒铁水中碳，锰，钒的选择氧化受温度的影响图，表明，随着温度的升高，碳的氧化越来越剧烈；钒、锰的氧化在减弱。 关键词：低钒铁水 转化温度 热力学 FactSage ABSTRACT Vanadium is an important strategic resource, and its application is very extensive. China is big country, vanadium resources of natural resources have laid a solid material foundation ,As a result, Vigorously development of v extraction technology, deep processing products in China and the new application has a unique foundation and broad prospects. Now,As a process of converter process optimization of blast furnace, blast furnace with addition of vanadium titanium ore ratio decreases, To the converter results in the decrease of vanadium content in hot metal, vanadium put forward higher request, So innovation v extraction method, optimize the process technology and enhancing the technical levels of v, for panxi strategic significance for the comprehensive utilization of resources. This topic to understand and master Panzhihua molten conditions, based on such as temperature, oxidant effect on the molten vanadium,Learning the principles of molten vanadium.Studies using the Origin software FactSage and low Panzhihua vanadium hot metal V, P selective oxidation problems.Calculation of low vanadium vanadium hot metal transformation temperature, oxidant selection and temperature.Come to the selective oxidation of vanadium hot metal suitable oxidizing agent is selected experiments CO2,And calculate the transition temperature of vanadium 1361 ℃,Drawing the molten iron of low carbon vanadium, manganese, vanadium selective oxidation is affected by temperature diagram,Showed that as the temperature increases, more and more intense