毕业设计（论文）-荧光碳量子点的合成及其在Fe3+检测中的应用精选.docxVIP

荧光碳量子点的合成及其在Fe3+检测中的应用目 录摘要ⅠAbstractⅡ第1章 绪论11.1碳点的概述11.2碳点的发光机理21.3碳点的性质21.4碳点的制备方法41.5碳点的应用5第2章 实验材料与方法62.1主要原料和试剂62.2主要仪器62.3实验方法6第3章 结果与讨论93.1碳点的表征93.2 Fe3+及其他金属离子对碳点荧光强度影响的分析113.3金属 Fe3+离子的荧光猝灭机理14结 论15致 谢16参考文献17荧光碳量子点的合成及其在Fe3+检测中的应用摘要：荧光碳点具有优异的荧光特性、良好水溶性和低的生物毒性,近年来受到了研究者的广泛关注。尽管目前荧光碳点的制备方法如电弧放电、激光烧蚀、电化学氧化、燃烧热解、微波加热、载体合成等取得了一定的发展,但制备荧光碳点的碳源难以收集或价格昂贵,导致其大批量的生产受到限制,不利于它的广泛应用发展。基于此研究背景,我们以绿色无毒、来源广泛、廉价易得的生物质材料樱花花瓣为碳源制备荧光碳点,有望实现荧光碳点的大批量的生产,探讨了其详细的反应机理,并将其成功的用于金属离子检测领域。大量的文献报道证明碳点可用来检测金属离子是因为金属离子能够将碳点的荧光猝灭，并且由于碳点的毒性低，灵敏度高，化学及荧光性能优异，使其与传统方法相比拥有许多优势。本文首次采用樱花这种新颖的生物质碳源采用一步水热法制备荧光碳点，无需钝化修饰。分别通过用紫外吸收光谱（UV）、荧光发射光谱（PL）、X－射线粉末衍射光谱（XRD）、红外吸收光谱（FTIR）表征了碳点的光学性质及表面结构等情况。合成的碳点无毒无污染，并且稳定性高，水溶性好，分散性好。通过荧光分光光度法分析碳点与不同金属离子相互作用发现：低浓度金属离子对碳点的荧光强度作用不大,而Fe3+ 猝灭作用很强。说明了碳点可以作为荧光探针来定量检测Fe3+。且基于Fe3+ 对碳量子点的荧光猝灭效应,建立了一种简便、耗费低、稳定、环保的检测Fe3+ 的方法。关键词：荧光碳点 樱花 水热法 铁离子Synthesis?of?Fluorescent?Carbon?Dots?and?Their?Application?in?the Detection?of?Fe3+Abstract:Fluorescence carbon points have excellent fluorescence properties, good water solubility and low biotoxicity, and have been widely studied by researchers in recent years. Although the preparation of fluorescent carbon points such as arc discharge, laser ablation, electrochemical oxidation and burning of pyrolysis synthesis, microwave heating, carrier has obtained certain development, but the preparation of fluorescent carbon carbon source is difficult to collect or expensive, due to its mass production is restricted, not conducive to the advancement of its wide application. A large number of literature reports prove point carbon can be used to detect metal ions because of metal ions, the fluorescence quenching of carbon points, and because the carbon point of low toxicity, high sensitivity, chemistry and fluorescence performance is excellent, compared with the traditional method has many advantages. For the first time, this paper adopts the novel biomass carbon source of sakura, which uses a water and heat method to prepare fluorescent carbon sp