[企业管理]LTO Lecture.ppt

Outstanding rate capability (Figure a and c) Superior cycling performance Low ionic and electronic resistance (Figure d and e) Fast kinetics Electrochemical performance of LTO/C nanostructure The discharge capacity of the LiFePO4/C core–shell nanostructured electrode was 156 mA h g?1 at a rate of 1 C, and delivered a capacity of ~118 mA h g?1 at a high rate of 20 C (3.4 A g?1), thereby indicating its high power performance. The LiFePO4/C core–shell nanostructured electrode also possessed superior cyclic stability (only ~8% capacity loss after 1000 cycles at a high rate of 10 C) Electrochemical performance of LFP/C nanostructure Carbon-free strategy High tap density Surface stability 四. Li4Ti5O12的表面修饰与改性 L.F. Shen, X.G. Zhang,* G.Z. Cao,* et al, Adv. Mater. 2012 DOI:10.1002/adma.201203151 Experiment procedure Growth of Na2Ti2O5·H2O NWAs on Ti foil Na+ exchange with H+ Chemical lithiation of H2Ti2O5·H2O NWAs Annealing treatment in Ar/H2 Figure 1. Schematic illustration for the fabrication of H-LTO NWAs 氢化 Li4Ti5O12 (H-LTO) 纳米线 Advantages: Surface area Electronic conductivity Direct connection Avoiding use of binders or AB Diameter : 90 nm Length: 8 μm Hierarchically porous nanowire composed of many small nanoparticles instead of the conventional single-crystal nanowire, Figure 2. (a, b) Cross-sectional SEM images of H-LTO NWAs annealing at 600°C; (c, d) TEM images of H-LTO NWAs annealing at 600°C. Self-supported H-LTO electrode architecture Figure 3. (a) XRD pattern of H-LTO NWAs and LTO NWAs annealing at 600°C; (b) Overlay of normalized Ti 2p core level XPS spectra of H-LTO NWAs and LTO NWAs, together with their difference spectrum (“H-LTO NWAs” minus “ LTO NWAs”). XRD Analysis of H-LTO Nanowires An additional peak appeared at ~531.9 eV was attributed to the presence of Ti?OH bonds. Two extra peaks appeared at ~463.3 and ~457.6 eV are attributed to Ti 2p1/2 and Ti2p3/2 peaks of Ti3+, suggesting the Ti3+ sites were successful created in H?LTO NWAs during h