Electron Spin Resonance Spectroscopy电子自旋共振谱.pdfVIP

Mol. Sieves (2004) 4: 295–335 DOI 10.1007/b94238 Electron Spin Resonance Spectroscopy Bert M. Weckhuysen 1 · Ralf Heidler2 · Robert A. Schoonheydt2 1 Departement Anorganische Chemie en Katalyse, Debye Instituut, Universiteit Utrecht, Sorbonnelaan 16, 3508 TB Utrecht, The Netherlands 2 Centrum voor Oppervlaktechemie en Katalyse, Departement Interfasechemie, K.U. Leuven, Kasteelpark Arenberg 22, 3001 Heverlee, Belgium Abstract. The theoretical principles of the ESR technique and its application in the field of mol- ecular sieve science are reviewed. The first part of this chapter focuses on the basic principles and instrumentation of the ESR, ENDOR, ESE and ESEEM techniques. Special attention will be given to spectral simulation and quantitative analysis of ESR spectra. In the second part, the general features of the ESR spectra of transition metal ions and paramagnetic clusters in molecular sieves are presented and discussed. In addition, some remarks will be made about the use of paramagnetic molecules, such as NO. 1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 296 2 Principles and Practice of ESR . . . . . . . . . . . . . . . . . . . . . 297 2.1 Basic Principles and Magnetic Interactions . . . . . . . . . . . . . . 297 2.2 Instrumentation and Signal Generation . . . . . . . . . . . . . . . . 300 2.3 Quantitative Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . 304 2.4 Spectrum Simulation . . . . . . . . . . . . . . . . . . . . . . . . . . . 306 2.5 Modern ESR-Related Techniques: ENDOR and Pulsed ESR