Progress in Organic Coatings Volume 66 Issue 4Pages 412 419有机涂料进展卷期页.pdfVIP

Progress in Organic Coatings 66 (2009) 412–419 Contents lists available at ScienceDirect Progress in Organic Coatings j o u rn al h omepage: w w w. elsev /locate/porgcoat Synthesis and characterization of hyperbranched photosensitive polysiloxane urethane acrylate Fang Sun a,b,∗ , Jin Shi a,b , Hong-guang Du a,b , Jun Nie a,c a State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, PR China b College of Science, Beijing University of Chemical Technology, Beijing 100029, PR China c College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, PR China a r t i c l e i n f o a b s t r a c t Article history: A novel hyperbranched photosensitive polysiloxane urethane acrylate (HBPSUA) based on hyperbranched Received 23 February 2009 polyesters (HBP-OH) has been synthesized. HBP-OH was synthesized from N,N-diethylol-3-amine Received in revised form 4 June 2009 methylpropionate as AB2 monomer and trimethylolpropane (TMP) as a core molecule. The structure Accepted 6 September 2009 1 of the oligomer was characterized by FTIR, GPC and H NMR. The molecular weight of the oligomer is about 10,000 and the viscosity is 4446 cps at room temperature. The HBPSUA possesses good compat- Keywords: ibility with most of acrylate monomers. The effect o