Transesterification Acylation Reactions Catalyzed by Molecular Catalysts分子催化剂催化酯交换酰化反应.pdfVIP

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Transesterification Acylation Reactions Catalyzed by Molecular Catalysts分子催化剂催化酯交换酰化反应.pdf

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REVIEW A Transesterification/Acylation Reactions Catalyzed by Molecular Catalysts a b b Transesterification/Acylation Reactions Catalyzed by Molecular CatalystsGabriela A. Grasa, Rohit Singh, Steven P. Nolan* a Johnson Matthey Catalysts Chiral Technologies, 28 Cambridge Science Park, Milton Road, CB4 1FP, Cambridge, UK b Department of Chemistry, University of New Orleans, New Orleans, LA 70148, USA Fax +1(504)2806445; E-mail: snolan@uno.edu Received 20 January 2004; revised 16 February 2004 or cleavage of acid-sensitive functional groups. On the Abstract: A survey of catalysts able to mediate the transesterifica- other hand, tertiary phosphines suffer from poor air-stabil- tion/acylation reaction is presented. Metal and organic catalysts are capable of facilitating this important transformation. ity, toxicity, and flammability. Transesterification (Scheme 1, equation 4) represents a mild and versatile al- 1 Introduction ternative to esterification reactions between an acid and an 2 Transesterification Reactions Catalyzed by Lewis Acids 2.1 Lanthanide (Sm) Catalysis alcohol (Scheme 1, equation 1). This transformation takes 2.2 Tin Catalysis place via an alkoxy moiety exchange between an