Progress in Organic Coatings Volume 66 Issue 3Pages 291 295有机涂料进展卷期页.pdfVIP

Progress in Organic Coatings 66 (2009) 291–295 Contents lists available at ScienceDirect Progress in Organic Coatings j o u rn al h omepage: w w w. elsev /locate/porgcoat Synthesis of isophorone diisocyanate (IPDI) based waterborne polyurethanes: Comparison between zirconium and tin catalysts in the polymerization process H. Sardon, L. Irusta, M.J. Fernández-Berridi ∗ Departamento de Ciencia y Tecnología de Polímeros, Facultad de Química, UPV, P.O. Box 1072, 20018 San Sebastián, Spain a r t i c l e i n f o a b s t r a c t Article history: In this work, a comparative study of the catalytic activity of tin and zirconium compounds in the poly- Received 24 December 2008 merization of isophorone diisocyanate (IPDI) based waterborne polyurethanes is presented. Zirconium Accepted 6 August 2009 acetyl acetonate is much less toxic than the commonly used dibutyltin diacetate but it is deactivated in the presence of acid groups. Nevertheless, acid groups are commonly used in the synthesis of waterborne Keywords: polyurethanes and therefore these groups have to be neutralized in advance for carrying out the synthe- Waterborne polyurethanes sis using the zirconium catalyst. Moreover, FTIR and 13C NMR results have shown that in the presence of Zirconium and tin catalysts triethyl amine and tin catalyst, the secondary isocyanate group is more reactive than the primary group, IPDI reactivity Triethylamine whi