Progress in Organic Coatings Volume 66 Issue 3Pages 314 320有机涂料进展卷期页.pdfVIP

Progress in Organic Coatings 66 (2009) 314–320 Contents lists available at ScienceDirect Progress in Organic Coatings j o u rn al h omepage: w w w. elsev /locate/porgcoat Electrochemical study of protective behavior of organic coating pigmented with zinc aluminum polyphosphate as a modified zinc phosphate at different pigment volume concentrations R. Naderi, M.M. Attar ∗ Polymer Engineering Department, AmirKabir University of Technology, P. O. Box: 15875-413, Tehran, Iran a r t i c l e i n f o a b s t r a c t Article history: Electrochemical impedance spectroscopy was employed to evaluate protective performance of the Received 18 March 2009 solvent-borne epoxy coatings pigmented with zinc aluminum polyphosphate as a representative of Received in revised form 11 August 2009 phosphate-based anticorrosion compounds at different Lambda values. Furthermore, the effective ratio Accepted 12 August 2009 of the pigment volume concentration (PVC) to the critical pigment volume concentration (CPVC) was determined. To compare the function of zinc aluminum polyphosphate and zinc phosphate incorporated Keywords: into coatings, electrochemical noise method as well as electrochemical impedance spectroscopy was Polyphosphate-based anticorrosion taken into consideration. The trend and magnitude of charge transfer, coating and noise resistances plus pigment Electrochemical impedance spectroscopy