FTIR原理使用及附件SP100.pptVIP

* 31 ATR 反射附件 （Attenuated Total Reflection） SAMPLE 样品 Incident Radiation 入射光 Reflected Radiation 反射光 PRIZM Evanescent Wave 驻波 ? 波数（λ） (cm-1) 入射角 （θ） 晶体折射率（n1） 样品折射率（ns） 穿透深度 （D）微米 1000cm-1 45 ZnSe 2.43 1.3 1.4 1000cm-1 45 ZnSe 2.43 1.5 1.9 1000cm-1 60 ZnSe 2.43 1.5 1.1 3000cm-1 45 ZnSe 2.43 1.5 0.48 1000cm-1 45 Ge 4.00 1.5 0.66 全反射光束穿透样品层的厚度 λ D = ————————————— 2πn1 [sin2 θ－(ns/n1) 2]1/2 （1）样品折射率越高，穿透深度越深 （2）入射角θ越大，穿透深度越浅 （3）光谱波数越高，穿透深度越浅 （4）晶体折射率越大，穿透深度越浅 有机物折射率一般小于1.5，所以ATR测试样品的深度约1 微米。 ATR 反射附件 ATR 反射附件 ATR附件测试的要点： 样品与高折射率晶体表面紧密接触。 样品与驻波发生作用产生光谱吸收。 光谱是近表面区域的。 吸收强度取决于接触程度，反射次数和晶体特性。 Pressure Diamond Sample 1 mm 0 单次反射ATR附件光路图 Diamond/ZnSe/KRS-5 /Ge ATR 反射附件 Sample IR Metal plate 多次反射ATR 聚乙烯食品包装袋 ATR 反射附件 黑色橡胶 ATR 反射附件 ATR 反射附件 晶体种类Crystal Materials ZnSe refractive index 2.4 Diamond refractive index 2.4 KRS-5 refractive index 2.4 Germanium refractive index 4.0 ZnSe (Zinc Selenide) Crystals 硒化锌晶体清洗 Cleaning ZnSe Crystals Avoid contact of the crystal with oxidizers and acids. ZnSe can be cleaned in pure dry acetone or methanol using a soft, lint free cloth and drying in a current of warm air so that there is no possibility of condensation forming on the crystal. Other suitable solvents are petroleum ether and hexane. It may also be cleaned in some commercial laboratory detergents, but they must be neutral. Alkaline solutions will slightly etch the surface, and acids will severely attack the material. A final rinse in distilled water and drying in a current of warm air is recommended. Thanks P Save a tree...please do not print this document unless you really need to * * * 认识未知掌握规律。 * * * 3 * 4 * 5 * We can see the basic elements of the Michelson interferometer this section through our Dynascan interferometer. The beam enters on the left and is split into two arms by the beamsplitter. One beam is reflected back by the adjustable mirror which is adjustable to set the parallelism and the o