《聚合反应原理专论》 chapter6 （中科大研究生教学课件）.pptVIP

Chapter 7 Characteristics of condensation polymerization Condensation polymerization based on the reactions of functional groups of the monomers Monomers are consumed fast Polymers are formed only in high conversion Uncontrolled molecular weight Uncontrolled molecular weight distribution Polymerization behavior Principles of chain-growth condensation polymerization The change of the substituent effect induced by bond formation of the monomer drives the reactivity of the polymer end group to become higher than that of the monomer. 2. In condensation polymerization based on a coupling reaction w