试验条件对X射线衍射物相定量分析结果的影响-分析测试.PDFVIP

2008 2 Vol. 27, No. 1 February 2008 ROCK AND M IN ERAL ANAL YSIS 6062  : 025425357 (2008) 0120060203 X 1 1 2 , , ( 1. , 750021; 2. , 213000)  : X , K X , , X X  : X; ; ;   : P575. 5 : B Effect of Exper im en ta l Cond ition s on X2ray D iffractom etr ic Quan tita tive Pha se Ana lysis 1 1 2 FANG Jun 2zhuo , ZHAN G X ia , XU Chong 2fu ( 1. Ke y Labo ra to ry o f Ene rgy R e so u rce s Chem ica l Eng inee ring, N ingxia U n ive rsity, Yinchuan750021, C h ina; 2. J ia ng su Te chno lo g ica l Co llege , C hangzho u 213000, C h ina ) Abstract: The matrix effect on X2ray diffractometric quantitative multi2phase analysis was studied through experiments. Influential factors such as K value ( I / Ic ) , diffraction signal intensity, samp le particle size for all phases and power of X2ray tube used were emphasized. The results showed that qualitative analysiswas the p rerequisite of quantitative analysis. Some measures, including using integral intensities, making samp le particle size as fine and homogeneous as possible in all phases, using X2ray tube power and suitable scanning speed, were taken and the accuracy of quantitative X2ray diffraction phase phase analysis was remarkably imp roved. Key words: X2ray diffraction; diffraction intensity; quantitative phase analysis; expe