硕士论文-PVC防腐套管的EP粘结剂的研究参考.docVIP

摘 要 聚氯乙烯是一种重要的耐腐蚀塑料，在管线等化工方面具有广泛的应用。然而其本身耐温性方面较差。如何在保留其耐腐蚀性的同时，扩大其在应用范围是急需解决的问题。本论文的研究的基本设想是：主要通过对在金属与PVC管之间的胶粘剂改性来解决上述问题。为此本论文侧重研究PVC与金属管材间的胶粘剂的粘结性进行研究。 本论文采用分子设计的思想，充分考虑工业生产耐温性的要求，利用耐热的芳香胺选用固化促进剂室温下固化选用聚酰胺为增韧剂对环氧树脂进行改性用硅烷偶联剂KH-550对蛭石进行改性并通过扫描电镜(SEM)、红外(FT-IR)接触角测试等对蛭石表面的物理化学性能进行了表征(TG)、扫描电镜、红外图谱以及胶体剪切强度等性能测试手段同时考察了硅烷偶联剂接枝改性PVC对粘结强度的影响。的主要结果如下： 选用混合芳香二胺类固化剂（DDM:m-PDA=2:3）固化树脂正丁醇为稀释剂，双酚A为固化促进剂，用量分别占树脂胶体的15%、20%、10%时，胶体的性能达到最佳值。通过热重分析和胶体剪切强度分析确定聚酰胺的最终用量为10%；对胶粘剂进行EIS）技术分析说明胶体的耐蚀性能良好。SEM结果显示蛭石表面的性能及其在胶体中的分散性得到了改善。通过胶体的胶粘性能和隔热性能测试确定填料的添加量为10%时胶体的隔热性能和粘接性能最好。对添加10%填料的胶体做热重分析，确定其适用温度并分析填料对胶体耐热性能的影响。通过阻抗分析，说明填料的加入可以提高胶体的耐蚀性能。采用水和乙醇的混合溶剂水解较水或乙醇单一溶剂水解得到的硅烷膜能好经过硅烷偶联剂改性的PVC，粘结性能得到提高 关键字：环氧胶粘剂；改性；硅烷偶联剂；蛭石；PVC；防腐 Abstract PVC is an important corrosion-resistant plastic, has a wide range of applications in the pipeline and other chemicals. However, it is poor in terms of heat resistance. While retaining their corrosion resistance, how to expand its scope of application is an urgent problem. The basic idea of this paper studies is: Mainly through modifying the adhesive between the PVC pipe and metal to address these issues. This thesis research focus on the study of adhesive bonding between PVC and metal tube. In this thesis, the idea of molecular design is taken.And r the requirements of heat resistance in industrial production is fully consided.Using the heat-resistant aromatic amineas as curing agent; selecting curing accelerator to achieve room temperature curing;Polyamide is used for the toughening modify of the epoxy resin; And using the small thermal conductivity vermiculite as filler.Silane coupling agent KH-550 was used to modify vermiculite. And the physical and chemical properties of vermiculite surface were characterized by scanning electron microscopy (SEM), infrared (FT-IR) and contact angle test.The bonding effect and mechanism are studied by thermogravimetric analysis(TG), scanning electron microscopy(SEM), infrared spectrum (IR), electrochemi