硕士均相催化原理与应用-4.ppt

氢硅烷化反应 The addition of a silicon compound such as R3SiH to alkene functionality, as shown by reaction 1, is used widely in silicone polymer manufacture and is called the hydrosilylation reaction. （1） 催化剂： H2PtCl6或改性的化合物 Proposed hydrosilylation echanism with soluble catalysts of platinum or rhodium 氢硅烷化反应 C－C键偶联反应 Soluble palladium complexes catalyze a large number of reactions of the type A and B. These reactions are often referred to as Heck reactions. A B 氧化反应 WACKER 氧化 WACKER反应的多样性： * 均相催化原理与应用Part 4 华东理工大学 侯震山 2015.11.20 催化原理课程 复习上一节内容： 配位催化的概念 配体的配位和解离反应 氧化加成和还原消除反应 插入反应 和金属结合的配体的