MgFe水滑石类化合物的制备与表征Preparation.pdf

OI :10.15952/ki.cjsc.2002.06.018 　　　　　　　　 　Chinese Journal of Synthetic Chemistry — 531 — MgFe 水滑石类化合物的制备与表征 王　岚, 陈慧琴, 詹正坤 (, 　430079) :MgFe 。 MgFe Mg/Fe 。X-, Mg/Fe 2, 3 4 、。 - MgFe , 175℃ 353℃。 　　:MgFe ;; :O611.4, O643.36 :A :1005-1511(2002)06-531-03 Preparation and Characterization of Magnesium-iron Hydrotalcite-like Compounds WANG Lan, 　CHEN Hui-qin, 　ZHAN Zheng-kun (epartment of Chemistry, Central China Normal University, Wuhan 430079, China) Abstract:A series of MgFe hydrotalcite-like compounds were synthesized by coprecipitation. XR , TA, TG and chelatometry were used to research the composition and structure of the products.The results showed that the hydrotalcites with Mg/Fe molar ratios of 2 to 4 have the nice crystal form and high purity. Keywords:MgFe hydrotalcite-like compounds;synthesize;structure 　　(Hydrotalcite, HT ) 、250mL [1] Mg (OH)2 , , 60℃±1 ℃, , 、 pH 。 80℃4 2+ 3+ Mg , Al 、 。, , 80℃。 (Hydrotalcite-like com- [2] 1.2　表征 pounds, HTLCs) 。 [3] XR /MAX-RB X- , , (40kV, 80mA, Cu , 0. MgFe , 15406nm);TG- TA RSZ , 。 (α-Al O , 10 ℃/min)。 2 3 1　 Mg/Fe 。 1.1　水滑石类化合物的合成 2　 。1, 。 2.1　XR 测试 :2002-06-11 :(1965-), , , , 。 。T el:(027E- mial:wanglan202@