新颖白光发光二极体氟硫化物萤光粉之探索.PDFVIP

新穎 白光發光二極體氟硫化物螢光粉之 探索* Preparation, Luminescence, and Application of Three Novel Cerium(III)- Activated Fluorosulfide Phosphors for White-Light LEDs 1 2 吳 昀 錚 T.M. Chen, Y.C. Wu (WLED) Sol i d - st at e l i gh t in g h a s b e c om e th e main stream in illumination industries. This WLED research is attempted to investigate the color quality of white LED with respect to white LED Y2(Ca,Sr) hue tunability, color temperature, and color F S :Ce3+ α-YFS: Ce3+ β-YFS: Ce3+ rendering, which are critical to the quality of 4 2 lighting. We formulated three novel phosphors: LED Y (Ca,Sr)F S :Ce3+ 250- Y (Ca,Sr)F S :Ce3+ , α-YFS:Ce3+ and β-YFS: 2 4 2 2 4 2 400 nm 400-570 nm 553-590 Ce3+ . The Ce3+, which exhibit strong absorption nm α-YFS: Ce3+ 300-600 nm in the spectral rage of 250-460 nm and emit 670 nm yellow-orange, yellowish green, and red colors, LED β-(Y0.95Ce0.05)FS r esp ectiv ely. Whit e-light LED s h av e b een CaAlSiN3 :Eu2+ 90 fabricated by properly integrating LED chips, (0.384,0.399) 4,2 13K LED fluorosulfides and complementary phosphors. The white-light LEDs show excellent color LED qualities. 關鍵詞：Y ( C a Sr ) F S :C e 3 + α- Y F S :C e 3 + Key words: Y (Ca Sr)F S :Ce3+ ; α-YFS:Ce3+ ; 2 , 4 2 2 , 4 2 β-YFS:Ce3+ β-YFS:Ce3+ ; Phosphors; White- light LED 壹、前