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量子力学与实验七
CN Chapter 7
CT Selected Topics
A 7.1 Quantum Statistics
Quantum statistical mechanics is the branch of physics dealing with systems in mixed states;
it is the quantum analogue of classical statistical mechanics. It should be noted that sta-
tistics enters at two levels in quantum statistical mechanics: first, because of the statistical
interpretation of the wave function and second, because of our incomplete knowledge of
dynamical state of the system.
B 7.1.1 Density Operator and Ensembles
Question: How to describe quantum mechanically an ensemble of physical systems for which,
say ωα =60% are characterized by |α and the remaining ωβ =40% are characterized by
some other ket |β .
205
CHAPTER 7 – MANUSCRIPT
Example: a general state for S=1/2 system
|α = c+ |+ + c− |−
which characterizes a state ket whose spin is pointing some definite direction. We should
not confuse the probability weight of the states |+ and |− , ω ± , and |c± |2 .
Ensemble average and density operator.
Pure ensemble: |α
Mixed ensembles:
(1)
ω 1 α
(2)
ω2 α
(3)
ω3 α
. .
. .
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