成长分域组织と秩序.pdf

成長分域組織 と秩序-無 秩序構造 GROWTH SECTORAL TEXTURE AND ORDER-DISORDER STRUCTURE 秋 月 瑞 彦 (Mizuhiko Akizuki)* Crystals which possess three-dimensional atomic arrangements are formed through piling up of growth layers having anly two-dimensional atomic arrangement , when they grow from solution of low supersaturation. The two-dimensional atomic arrangements are different among different kinds of vicinal face. Thus, the orderings are controlled by the symmetry and the structure of the two-dimensional atomic arrangement exposed on the surface. If different ordering among different growth sectors which are formed through growth process are frozen as they appeared and not equilibrated after the cessation of growth, growth sectors showing different optical properties will be observed in a crystal. Many of the so-called optical anonraliel3 or sector textures observed among natural minerals may be accounted for on this mechanism In this paper, discussions- are made on this mechanism, taking several minerals as examples. Adularia, intermediate microcline, analcime and chabazite are representative minerals showing sectors which can be accounted for by AI/Si ordering. Also, topaz and garnet (Gr-And) exhibit similar features, which are explained by OH/F and Fe/Al ordering, respectively. 斜長石が安定である｡秩序一無秩序の相転移はこれらの 1.諸 言 鉱物の間で起る｡この相転移は三次元的であ るのに対 秩序一無秩序構造 は相転移 の問題 であ り,結晶構造 の し,成長時に結晶表面で生じる秩序一無秩序構造は二次 問題であったが,筆 者 はこれ を初 めて結晶成長 の問題 と 元的である｡従って,結晶成長で生じる秩序一無秩序構 して扱 った｡ 造は相転移で生 じる三次元的なものと著しく異なること 熱水鉱物 にはしばしば分域組織 を有す るものがあ り, がある｡ 一般 にその光学的対称性 は形態 の示す対称性 より低い｡ 今まで全く研究されて来なかった