甲醇汽油稳定性与馏程特性的研究.pdf

甲醇汽油稳定性与馏程特性的研究 摘 要 甲醇与汽油的相溶性与基础油的性能、温度、甲醇添加量有很大关系。对比 ＃ 了甲醇与汽油的理化特性，应用低温反应器，以市售90 汽油为基础油探讨了不 同添加量的甲醇对混合燃料稳定性的影响，结果证明甲醇－汽油混合体系稳定性 较差，在实验研究范围内（10%～50% ），0℃左右即发生相分离现象。利用四种 助溶剂A 、B 、C、D （沸点均比甲醇高）探讨了甲醇－汽油体系稳定性的改善途 径。单独使用时助溶剂A效果最好，混合助溶剂综合性能更优。甲醇的添加对燃 料油馏程特性影响显著，添加量增大（10%～50% ），低沸点馏分增多。高沸点 助溶剂对混合燃料蒸馏特性具有改善作用。应用石油产品馏程测定器，利用四种 助溶剂A 、B 、C、D探讨了甲醇－汽油体系蒸馏特性的改善途径。单独使用时助 溶剂B效果最好，混合助溶剂综合性能与经济性更优。通过助溶剂种类及使用量 的选择，有望获得低温稳定性好、符合商用汽油馏程特性的新型车用燃料。 关键词: 甲醇汽油；相溶性；馏程；助溶剂 ３ 甲醇汽油稳定性与馏程特性的研究 Abstract The intermiscibility of methanol and gasoline is greatly related to the property of base oil, temperature and the additive amount of methanol. In this paper, the physicochemical characteristics of methanol and gasoline have been contrasted, and the effect of different additive amount of methanol on the stability of the fuel combination has been discussed by using the commercial 90 # gasoline as the base oil.The results show that methanol gasoline mixed system stability is poor, in the experimental study of range ( 10% ~ 50% ), and about 0 is the onset of phase separation phenomenon. Using four kinds of solvent A, B, C, D ( boiling point than the methanol high ) on the stability of methanol gasoline system improvements. When used alone, cosolvent A was the best solvent, mixed comprehensive performance is better. Methanol addition on fuel oil distillation characteristics influence significantly, adding quantity increases ( 10% ~ 50% ), the low boiling fraction number. High boiling solvent distillation characteristics of mixed fuel having improved effect. Application of distillation of petroleu