SiO2微粉悬浮液的剪切流变行为.PDFVIP

SiO 微粉悬浮液的剪切流变行为 2 陆成龙，邓承继，彭玮珂，祝洪喜，员文杰，李 君 (武汉科技大学，省部共建耐火材料与高温陶瓷国家重点实验室，武汉 430081) 摘要：利用流变仪对 SiO2 微粉悬浮液进行稳态剪切和动态剪切实验，通过同轴旋转剪切、 小振幅振荡剪切、大振幅振荡剪切3 种方式对悬浮液的剪切流变行为进行了表征，得到悬浮 液结构稳定性的动力学条件及结构破坏条件。结果表明：同轴旋转法可对悬浮液的结构强弱 进行定性判断，非牛顿系数n 能够表征悬浮液结构的强弱；小振幅振荡法能对悬浮液的结构 强弱进行定量分析，确定了悬浮液的线性黏弾区，获得了悬浮液结构开始破坏、开始流动时 的应变和剪切应力；大振幅振荡法实验下，Cox-Merz 经验公式适用于SiO 微粉悬浮液，能 2 够确定存储模量(G ＇)为零的状态，进而得到悬浮液结构完全被破坏时所需的剪切应力和剪 切速率。 关键词：流变性；二氧化硅微粉；悬浮液；结构 中图分类号：TQ175.1+3 文献标志码：A 文章编号：0454–5648(2014)09–– Rheological Behaviour of Fumed Silica Suspensions After Shearing LU Chenglong ，DENG Chengji ，PENG Weike ，ZHU Hongxi ，YUAN Wenjie，LI Jun (The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China) Abstract ：Suspensions of fumed silica were examined under steady shear and dynamic shear in a rheometer with coaxial rotation shear (CRS), small amplitude oscillatory shear (SAOS) and big amplitude oscillatory shear (BAOS) in order to characterize the rheological behavior of suspensions after shearing. The dynamics of the structure and the structure damage condition of suspensions were obtained. The structure of suspensions was estimated qualitatively by CRS, and its strength was determined by the non-Newtonian index. The structure of suspensions was estimated quantitatively by SAOS, and the linear viscoelastic range (LVE-range) was obtained. The strain and stress were ascertained in the beginning of structure destruction and flow. The rheological behavior of the suspensions of fumed silica under BAOS condition follows the Cox-Merz empirical model. The stress and shear rate were ascertained at the zero value of store modulus when