电化学分析吉林大学6.ppt

EC过程： Solution K =k-1/k1 Electrode A1 ? ne ? A2 这是一个催化过程。 Fig.6.10. The effect of coupled homogeneous reactions on electrode reactions illustrated for an oxidation. Mechanisms (a) CE (b) EC (c) EC’ Absence of homogeneous reaction (----); presence (__). Preceding Reaction-前置反应－CrEr ?=(kf + kb)t 恒电势仪 potentiostat Summary of Behavior at Ultramicroelectrodes Although there are some important differences in the behavior of UMEs with different shapes, it is useful here to recollect some common features in the responses to a large-amplitude potential Step: First, at short time, wher