载金属离子的13X分子筛吸附噻吩的动态特性-高校化学工程学报.PDFVIP

21 1 No.1 Vol.21 2007 2 Journal of Chemical Engineering of Chinese Universities Feb. 2007 1003-9015(2007)01-0159-04 13X , , ( , 210009) 2+ 2+ 2+ + 13X Cu Zn Ni Ag 13X Φ10.5 mm×200 mm Zn2+-13X Ni2+ + -13XAg -13X Ag+ − 1 + -13X 60.20 mg⋅g Ag -13X 5 0 13X TQ028.3 TQ424.25 TE624.54 A Dynamic Characteristics of Thiophene Adsorption Adsorbed on 13X Loaded with Metallic Ions JU Shen-gui, YAN Wu-min, ZENG Yong-ping (College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China) 2+ 2+ 2+ + Abstract: The adsorbents of 13X loaded with Cu Zn Ni Ag separately were prepared, and the dynamic characteristics of thiophene absorption on the adsorbents prepared and 13X were studied. The breakthrough curves of thiophene were measured by using a column (Φ10.5 mm200 mm) filled with 13X and 13X loaded with Cu2+ 2+ 2+ + 2+ 2+ + Zn Ni Ag , respectively. The used adsorbents of Zn -13XNi -13X and Ag -13X were regenerated by heating method and the breakthrough curves of thiophene on those regenerated adsorbents were also measured. The results show that the Ag+-13X is the better one since its adsorption amount of thiophene is 60.20 mg⋅g− 1 which is the largest among those adsorbents mentioned above, and after regeneration of the used Ag+-13X, the concentration of thiophene in the exit